AP Chemistry Exam Questions

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Chemistry Paper 1 Questions and Answers - KCSE 2021 Past Papers

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  • Draw a labelled diagram showing the atomic structure of  24 12 mg. (2 marks)
  • The atomic number of phosphorus is 15. Draw a dot (•) and cross (x) diagram for the compound formed when phosphorus reacts with chlorine, atomic number 17. (1 mark)
  • State the condition under which a Bunsen burner produces a luminous flame. (1 mark)
  • Write an equation for the reaction that takes place in a luminous flame assuming the laboratory gas is butane. (1 mark)
  • One of the regions in the non-luminous flame is the unburnt gas region. Describe how the presence of this region can be shown using a wooden splint. (1 mark)
  • The elements sodium, magnesium and aluminium belong to group I, II and III respectively. Select the element with the highest electrical conductivity and give a reason. (1 mark)
Compound Anode Cathode
Concentrated sodium chloride    
Molten sodium chloride    
  • State two observations made during the reaction. (1 mark)
  • State and explain another observation made when a drop of phenolphthalein is added to the mixture in the beaker. (1 mark)
  • Explain why it is not advisable to carry out this experiment using potassium metal. (1 mark)
  • Describe how a pure sample of copper(II) nitrate crystals can be prepared using recycled copper wire. (3 marks)
  • Draw a setup of the experiment. (2 marks)
  • Write an expression to show how the percentage of air used is calculated at the end of the experiment (1 mark)

1

  • lithium (1 mark)
  • magnesium (1 mark)
  • Predict the atomic radius of calcium. (1 mark)
  • Give the name of compound D. (1 mark)
  • Draw two possible structures of the products formed. (2 marks)

17

  • State the precaution that should be taken in carrying out the experiment. Give a reason. (1 mark)
  • State the observations made in the boiling tube. (2 marks)
  • Give the enthalpy change per mole of ammonia. (1 mark)
  • Increase in temperature. (1 mark)
  • Finely divided iron. (1 mark)

2

  • Identify solid E. (1 mark)
  • Name the type of reaction that takes place in chamber 1. (1 mark)
  • Write an equation for the reaction that takes place in chamber 2. (1 mark)

3

  • Compound H. (1 mark)
  • Compound J. (1 mark)
  • State the conditions necessary for H and J to react. (1 mark)
  • Draw the structure of rhombic sulphur. (1 mark)
  • Describe the observations made when rhombic sulphur is heated from room temperature until it boils. (1 mark)

4

  • Calculate the enthalpy change when 5:12 gof potassium sulphate is completely dissolved in water (K = 39:0;5=32,0; 0 - 16.0)(1 mark)
  • State Gay-Lussac's law. (1 mark)
  • Write an equation for the reaction. (1 mark)
  • Calculate the total volume of the gases at the end of the reaction. (3 marks)

5

  • Describe how dilute nitrie(V) acid and blue litmus papers can be used to distinguish between solid samples of sodium carbonate and sodium sulphite. (3 marks)
  • Describe how propanone can be used to extract a pure sample of sunflower oil. (2 marks)
  • State why sodium hydroxide solution is not suitable for the extraction of sunflower oil. (1 mark)
  • dilute acid. (1 mark)
  • concentrated acid. (1 mark)

6

  • Write a nuclear equation for the formation of nuclide K from nuclide X. (1 mark)
  • The half-life of nuclide X is 47 minutes. Determine the percentage of nuclide X that remains after 188 minutes. (2 marks)
  • Other than the cost of electricity, give another reason why this method is expensive. (1 mark)
  • Calculate the mass of aluminium obtained when a current of 20A is used for 5 hours. (1 Faraday - 96500 C; Al - 27.0)(2 marks) 
  • Articles made of copper turn green when left exposed in air over a long period of time. (1 mark)
  • Addition of aqueous ammonia to a solution containing copper(II)ions produces a deep blue solution (1 mark)
  • State what is meant by relative atomic mass of an element. (1 mark)
  • A compound of carbon and element X with formula, CX, contains 3.6% carbon by mass. Calculate the relative atomic mass of X. (2 marks)
  • Complete the following equation to show the reaction that takes place. (1 mark) H 2 0 2 0 4
  • Name another reagent that can be used to prepare carbon(II) oxide by dehydration (1 mark)

7

  • Complete the setup in Figure 6 to show how nitrogen gas can be collected. (2 marks)
  • The nitrogen prepared using this setup is purer than that obtained from air. Give a reason. (1 mark)
Bond Bond Energy kJ/mol
N-H 388
N-N  163
O=O 496
N≡N 944
O-H 463
Reduction equations Eº/V 
CI  + 2e→2CI +1.36 
Br +2e→2Br   +1.07 
I + 2e→21 +0.54 
  • Give a reason why potassium iodide is added to table salt

chemistry essay answer 2021

MARKING SCHEME

18

  • When airhole/collar is closed or fully closed 
  • CH 4(g)  + 4O 2(g)  → C (s)   + 3CO (g)  + CO (g)  +5H 2 O (I)  OR CH 4(g)  + 4O 2(g)  → C (s)   + CO (g)  + CO (g)  +5H 2 O (I) 

9

  • Aluminium It has 3 delocalised electrons while sodium and magnesium has one and two respectively
Compound Anode Cathode
Concentrated sodium chloride Chlorine or CL Hydrogen H
Molten sodium chloride Chlorine or CL Sodium Na
  • The piece of metal darts/floats
  • Melts into silvery ball
  • Production of effervescence/hissing sound
  • The beaker becomes warm
  • Solution turns pink because sodium hydroxide/alkaline solution is formed
  • Potassium reacts explosively with water/ more vigorously/ more violent
  • Heat the copper wire in air to form copper
  • Add excess copper (II)  oxide to dilute nitric acid
  • Filter to remove unreacted copper (II)  oxide
  • Heat the resulting solution to saturation
  • Allow it to cool to form crystals 
  • Dry/filter the crystals

10

  • Initial height of air column - Final height of air column                  Initial height of air column OR Initial height of water - Final height of water                  Initial height of water

11

  • Na = 2.8.1 Li = 2.1 Sodium has 3 energy levels while lithium has two or Li = 2 Na = 2.8.1
  • Mg = 2.8.2 Na = 2.8.1 The effective nuclear charge is higher in magnesium than sodium. Mg has a higher number of protons
  • 208± 2 Ithout showing on the graph Extrapolate to 20 on x-axis and mark to value
  • Propyne  prop 1 -yne prop -1,2-iodene
  • The experiment should be carried out in a fume chamber out in open since carbon (II)  oxide is poisonous
  • A white percipitate is formed which dissolves to form a colourless solution
  • - 92.4  ⇒ =46.2 KJmol -1    2
  • It lowers the yield of ammonia since the forward reaction is exothermic or backward reaction is endothermic
  • No effect A catalyst has no effect on the position of the equilibrium
  • Potassium magnate VII or maganese(iv) oxide lead(vi) oxide
  • Red ox/oxidation
  • CI 2 (g)  + 2NaOH → NaCl (aq)  + NaOCl (aq)  + H 2 O
  • 3-methylpentanol/ 3-methylpentanol
  • Butanoic acid
  • Concentrated sulphuric VI acid/ sulphuric acid
  • Warm/heat/ temperature between 3-6ºC

12

  • Yellow solid forms amber liquid As the temperature increases the liquid becomes darker and vicious Then it turns dark red/brown and less vicious

13

  • RFM of K 2 SO 4 = 174 moles of K 2 SO 4 =  5.22 / 174 = 0.03 ΔH = 0.03 x 23.8 = 0.714KJ
  • When gases react, they do so in volumes that bear simple ratios to one another and to the products if gaseous at constant temperature and pressure
  • 2NO (g)  + O 2(g)  → 2NO 2(g) 
  • 2NO + O 2  → 2NO 2  using ratio Volume of oxygen = 180 x 1                                     2 = 90cm 3 Volume of oxygen unreacted = 400 - 90 = 310 Volume of NO 2 = 18cm 3   Total volume = 310 + 180 = 490cm 3  
  • Any contact between 
  • Mg and hydrochloric acid
  • Mg and ethanoic acid
  • Using a stopwatch to show the difference
  • Conclusion - HCl takes a shorter time
  • Put a 6cm Mg ribbon in conical flask and add 50cm 3 HCl. Using a stopwatch, record the volume of gases collected at a time inferral e.g. 15cm 3
  • Repeat the experiment using 50cm 3  of ethanoic acid
  • More/higher volume of gas will be collected when HCl is used than ethanoic acid at same inferral of time OR The reaction will take a shorter time to completion when HCl is used than when ethanoic acid used
  • Place blue items at the mouth of test tubes
  • Both turn red
  • Thereafter one of them is bleached
  • The sample that produces bleaching on the litmus is sodium sulphite
  • Crush the sunflower seeds using motar and pestle
  • Add propane and stir
  • Leave the extract on sunlight for propane to evaporate leaving oil behind
  • It will react with oil to form soap
  • Moles of NaOH =  0.4 x 25 = 0.01                                1000 Moles of HNO 3 = 0.01 Molarity of HNO 3 = 0.01 x 1000                                      10
  • C 1 V 1 = C 2 V 2  1 x 500 = 15.9M   31.5
  • Add acid to water

15

  • 188 = 4halflives 100 - 50 - 25 - 6.25 OR x - ½x - ¼x -  1 / 8 x -  1 / 16 x % =  1 / 16  x 100 = 6.25%
  • The graphite anode has to be replaced periodically
  • Q = It = 20 x 5 x 60 = 360000 moles =  360000 = 1.244moles 3 x 96500 mass = 1.244 x 27 = 33.588g
  • Due to formation of copper (II)  carbonate. Since copper reacts with carbon (IV)  oxide/CO 2
  • Due to formation of complex ion of tetramine copper (II)  ions OR due to formation of tetramine copper  (II)  ions
  • Is the mass of one atom of an element compound to the mass of carbon - 12
Let RAM 7 x be n X  
RAM  12

 
n


96.4 = 4
  n   
0.3
% mass  3.6

96.4

96.4 = 4 x 0.3
  n
No. of moles  3.6 
 12
96.4
  n
n = 96.4
       1.2
  0.3 96.4
  n
 
Ratio 1 4 = 80.3
  • H 2 C 2 O 4  → CO (g)  + CO 2(g)  + H 2 O (I) 
  • Sodium methanate

16

  • It has impurities such as noble gases
  • N 2 H 4  + O 2  → N 2 + H 2 O Bonds broken 4 x 388 = 1552 1 x 163 = 163 1 x 496 = 496 = 2211 Bonds formed 1 x 944 = 944 2 x 463 = 1852 = -2796 Enthalpy of combination = -2796 + 2211 = 585KJmol - 
  • Br 2(aq)  + 2I - (aq)  → 2Br - (aq)  + I 2(aq) Br 2(aq)  + 2CI -  → No reaction  Bromine will oxidize iodide ions to iodine since it has more positive E θ    Bromine will not displace chlorine since E θ  for Cl -  is more positive
  • Potassium iodide is a source of iodine is needed to regulate functioning of thyroid gland

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A/L Chemistry Vivarana books by Ranga Gunarathna

November 9, 2021 By Hiran 1 Comment

Ranga Gunarathna has published a series of Chemistry vivarana (Analysis) books. These books contain complete examination papers (MCQ, structured essay and essay questions) and answers (marking schemes), explanations and answers to those questions.

You can order these books online from daraz .

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September 26, 2023 at 8:57 pm

Please add English medium chemistry books, specially past papers vivarana

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Chemistry 2021 WAEC Past Questions

The hydrolysis of proteins by diluting mineral acids produces 

  • C. amino acids
  • D. fatty acids

Which of the following oxide causes acid rain?

  • C. H\(_{2}\)O\(_{2}\)
  • D. NO\(_{2}\)

The ratio of carbon atoms of hydrogen atoms in a hydrocarbon is 1:2. If its molecular mass is 56, what is its molecular formula?

  • A. C\(_{3}\)H\(_{6}\)
  • B. C\(_{4}\)H\(_{8}\)
  • C. C\(_{2}\)H\(_{4}\)
  • D. CH\(_{2}\)

What is the relative molecular mass of the compound below?

[H = 1.0; C = 12.0; O = 16.0]

Cathodic protection of metals is based on

  • A. standard electrode potential of hydrogen
  • B. its electrical conductivity
  • C. nature of oxides formed
  • D. relative tendencies of oxidation
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G.C.E. Advanced Level (A/L) Chemistry Past Papers and Answers

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2022 A/L Chemistry Past Paper | Sinhala Medium

Gce advanced level 2022 chemistry sinhala medium paper quick download.

2022 A/L Chemistry Past Paper | Sinhala Medium

Get the 2022 A/L Chemistry paper in Sinhala Medium by downloading it as a PDF file. The Sinhala medium 2022 A/L Chemistry past exam paper is available for download. The exam took place on February 01st , 2023.

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